Problem:
Sync to new location or Sync to new location only (Don't redirect) is used.
Windows 7
Symptoms:
Windows Firewall has blocked some features of this program
Windows Firewall has blocked some features of rsync on all public, private and domain networks.
Name: rsync
Publisher: Unknown
Path: C:\Program files\profileunity\temp\pupsync\rsync.exe

Possible Resolution(s):
Insert exemption in to GPO:
Open GPO Management Editor, go to: Computer Configuration\Policies\Administrative Templates\Network\Network Connections\Windows Firewall
Edit this setting: Windows Firewall: Define inbound program exceptions
Enable.
Value: c:\Program Files\profileunity\temp\pupsync\rsync.exe:*:enabled:Rsync App
Option 2)
Create registry rule in configuration to add this value:
Filter: No Filter - Apply this to all
Action: Add Value
Process Action Post Login: False
Hive: HKEY_LOCAL_MACHINE
Key: SYSTEM\ControlSet001\Services\SharedAccess\Parameters\FirewallPolicy\DomainProfile\AuthorizedApplications\List
Data Type: REG_SZ
Value: C:\Program Files\ProfileUnity\Temp\PUPThinApp\rsync.exe
Data: C:\Program Files\ProfileUnity\Temp\PUPThinApp\rsync.exe:*:Enabled:rsync
Description: Set firewall rule to allow rsync
Disabled: False
Note: Path to application might vary depending on version or ProfileUnity.
Refrerence: https://technet.microsoft.com/en-us/library/cc766312
Product: ProfileUnity-FlexApp
Product Version: 6.5